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If you do have to de-ess the vocals, try to use a split-band de-esser rather than the simpler compressor with an equaliser in the side-chain, as the split-band approach produces fewer undesirable side effects. It’s always best to try to avoid sibilance by moving the mic slightly or by using a different mic, rather than trying to fix it afterwards. Pointing the mic slightly above or below the singer’s mouth sometimes helps.